Ap Biology Reading Guide Fred And Theresa Holtzclaw Chapter 22 Answers

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  A water molecule is a polar molecule in which opposite ends of the molecule have opposite charges. Water has a variety of unusual properties because of the attraction between polar water molecules. The slightly negative regions of one water molecule are attracted to the slightly positive regions of nearby water molecules, forming hydrogen bonds. Each water molecule can form hydrogen bonds with up to four neighbors. They form, break, and reform with great frequency. Each hydrogen bond lasts only a few trillionths of a second. At any instant, a substantial percentage of all water molecules are bonded to their neighbors, creating a high level of structure. Collectively, hydrogen bonds hold water together, a phenomenon called cohesion.

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  Cohesion among water molecules plays a key role in the transport of water and dissolved nutrients against gravity in plants. Water molecules move from the roots to the leaves of a plant through water-conducting vessels. As water molecules evaporate from a leaf, other water molecules from vessels in the leaf replace them. Hydrogen bonds cause water molecules leaving the vessels to tug on molecules farther down. This upward pull is transmitted down to the roots.

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  Adhesion, clinging of one substance to another, contributes too, as water adheres to the wall of the vessels. Surface tension, a measure of the force necessary to stretch or break the surface of a liquid, is related to cohesion. Water has a greater surface tension than most other liquids because hydrogen bonds among surface water molecules resist stretching or breaking the surface. Water behaves as if covered by an invisible film. Some animals can stand, walk, or run on water without breaking the surface. Water moderates temperatures on Earth. Water stabilizes air temperatures by absorbing heat from warmer air and releasing heat to cooler air. Water can absorb or release relatively large amounts of heat with only a slight change in its own temperature.

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  Atoms and molecules have kinetic energy, the energy of motion, because they are always moving. The faster a molecule moves, the more kinetic energy it has. Heat is a measure of the total quantity of kinetic energy due to molecular motion in a body of matter. Temperature measures the intensity of heat in a body of matter due to the average kinetic energy of molecules. As the average speed of molecules increases, a thermometer will record an increase in temperature. Heat and temperature are related, but not identical. When two objects of different temperatures come together, heat passes from the warmer object to the cooler object until the two are the same temperature. Molecules in the cooler object speed up at the expense of kinetic energy of the warmer object. Ice cubes cool a glass of pop by absorbing heat from the pop as the ice melts. While there are several ways to measure heat energy, one convenient unit is the calorie cal.

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  In many biological processes, the kilocalorie kcal is more convenient. Another common energy unit, the joule J , is equivalent to 0. Water stabilizes temperature because it has a high specific heat. Water has a high specific heat compared to other substances. For example, ethyl alcohol has a specific heat of 0. Water resists changes in temperature because of its high specific heat.

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  In other words, water absorbs or releases a relatively large quantity of heat for each degree of temperature change. Heat must be absorbed to break hydrogen bonds, and heat is released when hydrogen bonds form. Investment of one calorie of heat causes relatively little change to the temperature of water because much of the energy is used to disrupt hydrogen bonds, not speed up the movement of water molecules.

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  A large body of water can absorb a large amount of heat from the sun in daytime during the summer and yet warm only a few degrees. At night and during the winter, the warm water will warm cooler air. Therefore, ocean temperatures and coastal land areas have more stable temperatures than inland areas. Living things are made primarily of water. Consequently, they resist changes in temperature better than they would if composed of a liquid with a lower specific heat.

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  The transformation of a molecule from a liquid to a gas is called vaporization or evaporation. This occurs when the molecule moves fast enough to overcome the attraction of other molecules in the liquid. Even in a low-temperature liquid with low average kinetic energy , some molecules are moving fast enough to evaporate. Heating a liquid increases the average kinetic energy and increases the rate of evaporation.

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  Heat of vaporization is the quantity of heat that a liquid must absorb for 1 g of it to be converted from liquid to gas. Water has a relatively high heat of vaporization, requiring about cal of heat to evaporate 1 g of water at room temperature. This is double the heat required to vaporize the same quantity of alcohol or ammonia. This is because hydrogen bonds must be broken before a water molecule can evaporate from the liquid. As moist tropical air moves to the poles, water vapor condenses to form rain, releasing heat.

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  As a liquid evaporates, the surface of the liquid that remains behind cools, a phenomenon called evaporative cooling. This occurs because the most energetic molecules are the most likely to evaporate, leaving the lower—kinetic energy molecules behind. Evaporative cooling moderates temperature in lakes and ponds. Evaporation of sweat in mammals or evaporation of water from the leaves of plants prevents terrestrial organisms from overheating.

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  Evaporation of water from the leaves of plants or the skin of humans removes excess heat. Water is unusual because it is less dense as a solid than as a cold liquid. Most materials contract as they solidify, but water expands. Water begins to freeze when its molecules are no longer moving vigorously enough to break their hydrogen bonds. As ice starts to melt, some of the hydrogen bonds break, and water molecules can slip closer together than they can while in the ice state. Therefore, ice floats on the cool water below. This oddity has important consequences for life. If ice sank, eventually all ponds, lakes, and even the ocean would freeze solid. During the summer, only the upper few centimeters of the ocean would thaw. Instead, the surface layer of ice insulates liquid water below, preventing it from freezing and allowing life to exist under the frozen surface.

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  Water is the solvent of life. A liquid that is a completely homogeneous mixture of two or more substances is called a solution. A sugar cube in a glass of water will eventually dissolve to form a uniform solution of sugar and water. The dissolving agent is the solvent, and the substance that is dissolved is the solute. In our example, water is the solvent and sugar is the solute. In an aqueous solution, water is the solvent. Water is not a universal solvent, but it is very versatile because of the polarity of water molecules. However, its giant cellulose molecules are too large to dissolve in water.

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